Cuprous bromide CAS#7787-70-4
CAS Number: 7787-70-4
Chemical Formula: BrCu
Synonyms:
COPPER BROMIDE
COPPER(+1)BROMIDE
Bromocopper(I)
MOQ (Minimum Order Quantity): 1 FCL (Full Container Load)
Appearance: White Powder
Cuprous bromide CAS#7787-70-4
White powder or crystal. Turns green to dark blue on exposure to sunlight. Sinks and mixes slowly with water.
Cuprous bromide Chemical Properties |
Melting point | 504 °C(lit.) |
Boiling point | 1345 °C |
density | 4.71 g/mL at 25 °C(lit.) |
Fp | 1345°C |
storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
solubility | insoluble in acetone |
form | Powder |
color | Pale green to green |
Specific Gravity | 4.98 |
Water Solubility | Soluble in hydrogen bromide, hydrochloric acid, and ammonium hydroxide. Slightly soluble in water. Insoluble in acetone. |
Crystal Structure | Hexagonal, Wurtzite (Zincite) Structure - Space Group P 63mc |
Sensitive | Air Sensitive |
Merck | 14,2659 |
Solubility Product Constant (Ksp) | pKsp: 8.2 |
Exposure limits | ACGIH: TWA 1 mg/m3 |
Stability: | Stable, but may be air or light sensitive. Incompatible with alkali metals, strong oxidizing agents. |
InChI | 1S/BrH.Cu/h1H;/q;+1/p-1 |
InChIKey | NKNDPYCGAZPOFS-UHFFFAOYSA-M |
SMILES | [Cu]Br |
Hardness, Mohs | 2.5 |
CAS DataBase Reference | 7787-70-4(CAS DataBase Reference) |
NIST Chemistry Reference | Copper(I) bromide(7787-70-4) |
EPA Substance Registry System | Copper bromide (CuBr) (7787-70-4) |
Safety Information |
Hazard Codes | Xi |
Risk Statements | 36/37/38-22 |
Safety Statements | 22-24/25-26-37/39 |
RIDADR | 3260 |
WGK Germany | 3 |
F | 8-10-23 |
TSCA | TSCA listed |
HazardClass | 8 |
PackingGroup | III |
HS Code | 28275900 |
Storage Class | 11 - Combustible Solids |
Hazard Classifications | Acute Tox. 4 Dermal |
Hazardous Substances Data | 7787-70-4(Hazardous Substances Data) |
Product Application Of Cuprous bromide CAS#7787-70-4
It is used as effective catalyst for tetrahydropyranylation of alcohols. It can also be used in combination with palladium in catalytic synthesis of 3-haloindoles through annulation process. It is widely used in the synthesis of organic fine chemicals. The compound is widely used in the synthesis of organic compounds. It is also useful for copper-mediated coupling reactions. A silica gel support copper bromide hexa methyltriethylenetetramine complex has shown useful application for the atom transfer radical polymerization of methyl methacrylate in toluene.
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